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The Elusive Terminal Imido of Manganese( V )
Author(s) -
Eikey Rebecca A.,
Khan Saeed I.,
AbuOmar Mahdi M.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20021004)41:19<3591::aid-anie3591>3.0.co;2-z
Subject(s) - manganese , amination , nucleophile , chemistry , terminal (telecommunication) , photodissociation , polymer chemistry , medicinal chemistry , organic chemistry , catalysis , telecommunications , computer science
At last , terminal imido complexes of manganese( V ), the postulated intermediates in aziridination and amination reactions, have been prepared. The structurally well‐defined (imido)manganese( V ) corroles, 2 and 3 , are easily synthesized from manganese( III ) corroles with organic azides under photolysis conditions and react with electron‐rich nucleophiles such as organic phosphanes.