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Generation of Polyunsaturated Cumulene Chains by Unprecedented Insertions of the Ynamine MeCCNEt 2 in Ruthenium( II ) Allenylidene Complexes
Author(s) -
Conejero Salvador,
Díez Josefina,
Gamasa Maria Pilar,
Gimeno Jose,
GarcíaGranda Santiago
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020916)41:18<3439::aid-anie3439>3.0.co;2-w
Subject(s) - ruthenium , cumulene , chemistry , materials science , organic chemistry , molecule , catalysis
Three‐fold sequential insertion of the ynamine MeCCNEt 2 into ruthenium( II ) allenylidene complexes leads to the stereoselective formation of the polyunsaturated complex I .