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The Total Synthesis of Coleophomones B and C
Author(s) -
Nicolaou K. C.,
Vassilikogiannakis Georgios,
Montag Tamsyn
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020902)41:17<3276::aid-anie3276>3.0.co;2-p
Subject(s) - olefin metathesis , metathesis , ring closing metathesis , ring (chemistry) , stereochemistry , chemistry , organic chemistry , polymerization , polymer
Pushing the frontiers of olefin metathesis : As the coleophomones B ( 1 ) and C ( 2 ) differ only in the configuration of the Δ 16,17 double bond, ring‐closing metathesis was chosen as the method for their construction following an initially convergent route that diverges at a late stage.