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Singlet Delta Oxygen Production from a Gas–Solid Reaction
Author(s) -
Alfano Angelo J.,
Christe Karl O.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020902)41:17<3252::aid-anie3252>3.0.co;2-g
Subject(s) - hydrogen peroxide , halide , singlet oxygen , alkali metal , hydrogen , chlorine , oxygen , quenching (fluorescence) , chemistry , gas phase , photochemistry , inorganic chemistry , materials science , organic chemistry , physics , fluorescence , quantum mechanics
1 Δ‐O 2 can now be made safely and efficiently from gas–solid reactions between alkali‐metal peroxides and hydrogen halides [Eq. (1)]. This method avoids the liquid‐phase quenching and instability problems associated with the hydrogen peroxide/chlorine system.