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Vapor‐Induced Luminescence Switching in Crystals of the Syn Isomer of a Dinuclear (Bipyridine)platinum( II ) Complex Bridged with Pyridine‐2‐Thiolate Ions
Author(s) -
Kato Masako,
Omura Ai,
Toshikawa Asami,
Kishi Shinobu,
Sugimoto Yukihiro
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020902)41:17<3183::aid-anie3183>3.0.co;2-a
Subject(s) - luminescence , acetonitrile , platinum , chemistry , pyridine , ion , molecule , bipyridine , photochemistry , crystallography , crystal structure , organic chemistry , materials science , optoelectronics , catalysis
Remarkable vapochromic effects are observed in a dinuclear platinum( II ) complex, where changes in luminescence are facilitated in the presence of solvated organic molecules, such as acetonitrile and ethanol (see scheme).