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An Enantiomerically Pure Propeller‐Shaped Supramolecular Capsule Based on the Stereospecific Self‐Assembly of Two Chiral Tris(oxazoline) Ligands around Three Ag I Ions
Author(s) -
Kim HaeJo,
Moon Dohyun,
Lah Myoung Soo,
Hong JongIn
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020902)41:17<3174::aid-anie3174>3.0.co;2-6
Subject(s) - oxazoline , supramolecular chemistry , chirality (physics) , tris , stereospecificity , denticity , ligand (biochemistry) , chemistry , stereochemistry , crystallography , metal ions in aqueous solution , capsule , ion , physics , organic chemistry , crystal structure , biochemistry , biology , receptor , chiral anomaly , botany , fermion , nambu–jona lasinio model , quantum mechanics , catalysis
Self‐recognition of ligand chirality leads to the completely stereospecific self‐assembly of a propeller‐shaped supramolecular capsule induced by a rigid chiral tris(oxazoline) acting as a tris‐monodentate ligand and Ag I metal ions having a tetrahedral coordination geometry (the structure of one helical complex is shown).