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Synthesis of Cycloalkanones from Dienes and Allylamines through CH and CC Bond Activation Catalyzed by a Rhodium( I ) Complex
Author(s) -
Lee DaeYon,
Kim InJung,
Jun ChulHo
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020816)41:16<3031::aid-anie3031>3.0.co;2-x
Subject(s) - rhodium , allylic rearrangement , chemistry , formaldehyde , catalysis , chelation , amine gas treating , medicinal chemistry , polymer chemistry , double bond , organic chemistry
Formaldehyde in disguise : The allylic amine 1 is used as a masked form of formaldehyde in the rhodium‐catalyzed cyclization of dienes 2 . The reaction provides access to various cycloalkanones 3 through chelation‐assisted CH‐ and CC‐bond activation.