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Reaction of “[Mn II (CH 2 t Bu) 2 ]” with Bidentate Diimine Ligands: From Simple Base Adducts to CC Activation of the Ligand
Author(s) -
Riollet Virginie,
Copéret Christophe,
Basset JeanMarie,
Rousset Laurence,
Bouchu Denis,
Grosvalet Laurent,
Perrin Monique
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020816)41:16<3025::aid-anie3025>3.0.co;2-b
Subject(s) - diimine , denticity , ligand (biochemistry) , chemistry , adduct , stereochemistry , crystallography , crystal structure , catalysis , receptor , organic chemistry , biochemistry
Ligand transformations that depend on the substitution patterns of the diimine ligands occur upon their complexation with Mn II dialkyl complexes. For example the 1,3‐migration of the neopentyl unit from Mn to a carbon atom and the 1,2‐migration of the methyl in the putative intermediate 1 give the product 2 .