Premium
Aryl CH Activation by Cu II To Form an Organometallic Aryl–Cu III Species: A Novel Twist on Copper Disproportionation
Author(s) -
Ribas Xavi,
Jackson Deanne A.,
Donnadieu Bruno,
Mahía José,
Parella Teodor,
Xifra Raül,
Hedman Britt,
Hodgson Keith O.,
Llobet Antoni,
Stack T. Daniel P.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020816)41:16<2991::aid-anie2991>3.0.co;2-6
Subject(s) - disproportionation , aryl , copper , chemistry , organic chemistry , catalysis , alkyl
Simple triazamacrocyclic ligands react with copper( II ) salts under mild conditions to give the products of intramolecular aryl CH activation and metal disproportionation [Eq. (1)]. The novel organometallic Cu III complexes thus formed are stable under protic conditions.