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Synthesis and Characterization of the Neutral “Digallene” Ar′GaGaAr′ and Its Reduction to Na 2 Ar′GaGaAr′ (Ar′=2,6‐Dipp 2 C 6 H 3 , Dipp=2,6‐ i Pr 2 C 6 H 3 )
Author(s) -
Hardman Ned J.,
Wright Robert J.,
Phillips Andrew D.,
Power Philip P.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020802)41:15<2842::aid-anie2842>3.0.co;2-o
Subject(s) - order (exchange) , content (measure theory) , characterization (materials science) , reduction (mathematics) , computer science , arithmetic , chemistry , econometrics , economics , database , mathematics , materials science , nanotechnology , finance , mathematical analysis , geometry
A GaGa bond order considerably less than unity in the “digallene” Ar′GaGaAr′ (Ar′=2,6‐Dipp 2 C 6 H 3 , Dipp=2,6‐ i Pr 2 C 6 H 3 ; see structure) is indicated by its structure and solution behavior.