Premium
Mo V /Pyrophosphate Polyoxometalate: An Inorganic Cryptate
Author(s) -
du Peloux Charlotte,
Mialane Pierre,
Dolbecq Anne,
Marrot Jérôme,
Sécheresse Francis
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020802)41:15<2808::aid-anie2808>3.0.co;2-x
Subject(s) - polyoxometalate , pyrophosphate , chemistry , inorganic chemistry , organic chemistry , catalysis , enzyme
Interconnecting rings : The first pyrophosphate/Mo V complex Na 24 {Na 4 (H 2 O) 6 ⊂[(Mo 2 O 4 ) 10 (P 2 O 7 ) 10 (CH 3 COO) 8 (H 2 O) 4 ]}⋅97 H 2 O is synthesized in mild conditions, and has been characterized by X‐ray diffraction (see polyhedral representation) and 31 P NMR spectroscopy. This molecular compound is formed of two nearly perpendicular interconnected wheels, an unprecedented topology for an inorganic compound.