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Dinitrogen‐Bond Cleavage in a Niobium Complex Supported by a Tridentate Aryloxide Ligand
Author(s) -
Kawaguchi Hiroyuki,
Matsuo Tsukasa
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020802)41:15<2792::aid-anie2792>3.0.co;2-k
Subject(s) - reagent , niobium , chemistry , dimer , nitride , hydride , ligand (biochemistry) , bridging ligand , cleavage (geology) , bond cleavage , photochemistry , crystallography , crystal structure , materials science , organic chemistry , metal , catalysis , receptor , biochemistry , fracture (geology) , composite material , layer (electronics)
Nitrogen splits : The reaction of the linked aryloxide–niobium complex 1 with a hydride reagent under 1 atm of N 2 gave the nitride‐bridging dimer 2 . The origin of the nitride ligands has been confirmed to be N 2 by repeating the experiment under an atmosphere of 15 N 2 .