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Conversion of Hexafluoropropene into 1,1,1‐Trifluoropropane by Rhodium‐Mediated CF Activation
Author(s) -
Braun Thomas,
Noveski Daniel,
Neumann Beate,
Stammler HansGeorg
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020802)41:15<2745::aid-anie2745>3.0.co;2-c
Subject(s) - rhodium , regioselectivity , chemistry , stereochemistry , medicinal chemistry , organic chemistry , catalysis
Rapid and regioselective CF bond activation of hexafluoropropene occurs on reaction with 1 . Treatment of the resulting complex 2 with hydrogen yields the rhodium fluoro complex 3 and 1,1,1‐trifluoropropane ( 4 ).