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2,3,5,6‐Tetrafluorophenylnitren‐4‐yl: A Quartet‐Ground‐State Nitrene Radical
Author(s) -
Wenk Hans Henning,
Sander Wolfram
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020802)41:15<2742::aid-anie2742>3.0.co;2-u
Subject(s) - nitrene , ground state , delocalized electron , carbene , electron delocalization , molecule , chemistry , common ground , spin (aerodynamics) , photochemistry , atomic physics , physics , organic chemistry , thermodynamics , catalysis , communication , sociology
Elements of a carbene and a nitrene are linked by a common delocalized π electron in the molecule described here (see picture). The organic high‐spin molecule with a quartet ground state could be photochemically generated and spectroscopically characterized in an argon matrix at 3 K.