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Investigation of Reactive Intermediates of Chemical Reactions in Solution by Electrospray Ionization Mass Spectrometry: Radical Chain Reactions
Author(s) -
GriepRaming Jens,
Meyer Sven,
Bruhn Torsten,
Metzger Jürgen O.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020802)41:15<2738::aid-anie2738>3.0.co;2-x
Subject(s) - chemistry , electrospray ionization , radical , mass spectrometry , electrospray , ionization , electrospray mass spectrometry , analytical chemistry (journal) , chromatography , organic chemistry , ion
A useful tool for the investigation of synthetically important tributyltin‐mediated radical chain reactions is electrospray ionization mass spectrometry (ESIMS). A microreaction system is coupled online to the ESI source. Transient radicals were detected unambiguously by using MS/MS methods (see picture).