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Synthesis and Structure of (MeN)Ph 2 SCSPh 2 (NMe)
Author(s) -
Fujii Takayoshi,
Ikeda Tomio,
Mikami Toshie,
Suzuki Tetsuya,
Yoshimura Toshiaki
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020715)41:14<2576::aid-anie2576>3.0.co;2-8
Subject(s) - character (mathematics) , ab initio , crystal structure , crystallography , chemistry , double bond , computational chemistry , group (periodic table) , stereochemistry , organic chemistry , mathematics , geometry
Double ylidic character in the S‐C‐S bonds is apparent from the single‐crystal X‐ray analysis of the title compound (see structure). This electronic configuration was supported by ab initio calculations on a model compound in which the phenyl groups were replaced by methyl groups.