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Synthesis, Structure, and Redox Properties of Diphosphathienoquinones
Author(s) -
Murakami Fumiki,
Sasaki Shigeru,
Yoshifuji Masaaki
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020715)41:14<2574::aid-anie2574>3.0.co;2-k
Subject(s) - redox , cyclic voltammetry , crystallography , orange (colour) , chemistry , electrochemistry , inorganic chemistry , electrode , food science
The first diphosphaheteroquinoid compound , which contains two low‐coordinate phosphorus atoms and a thienoquinoid skeleton (see picture), was isolated as air‐stable orange crystals. Its quinoid nature was confirmed by X‐ray crystallography and cyclic voltammetry, which revealed the expected redox behavior.