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Synthesis and Structure of an Azatrisilacyclobutane and Its Precursor, a Novel Lithium Enamide Having a Tricyclic (LiNSiO) 2 Skeleton
Author(s) -
Antolini Floria,
Gehrhus Barbara,
Hitchcock Peter B.,
Lappert Michael F.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020715)41:14<2568::aid-anie2568>3.0.co;2-z
Subject(s) - chemistry , tricyclic , lithium (medication) , stereospecificity , propellane , silylene , silylation , stereochemistry , cyanide , halogen , skeleton (computer programming) , bicyclic molecule , organic chemistry , catalysis , computer science , programming language , endocrinology , medicine , alkyl , silicon
A novel reaction of a thermally stable silylene with 1 , obtained by regio‐ and stereospecific insertion of the α ‐halogen‐free adamantyl cyanide into the LiC bond of the bis(silyl)methyl compound Li[CH(SiMe 2 OMe)(SiMe 3 )], yielded the new azatrisilacyclobutane 2 . NN=1,2‐[( t BuCH 2 )N] 2 C 6 H 4 .