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Bridging the Gap between Polyoxometalates and Classic Coordination Compounds: A Novel Type of Hexavanadate Complex
Author(s) -
Piepenbrink Markus,
Triller Michael U.,
Gorman Neville H. J.,
Krebs Bernt
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020715)41:14<2523::aid-anie2523>3.0.co;2-#
Subject(s) - bridging (networking) , coordination complex , chemistry , nanotechnology , combinatorial chemistry , materials science , computer science , metal , organic chemistry , computer network
Cluster catalysts for directed oxygen transfer? In attempts towards the creation of novel catalytic systems for directed oxygen‐transfer processes a novel type of polyoxometalate cluster containing vanadium was synthesized. The first example of a polyoxovanadate composed of a hexavanadate molecular center and two reactive, exchangeable, vanadium‐centered complexes which are tilted towards the polyoxometalate center is presented (see picture).