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Reaction Principles and Crystal Structure Design for the Topochemical Polymerization of 1,3‐Dienes
Author(s) -
Matsumoto Akikazu,
Sada Kazuki,
Tashiro Kohji,
Miyata Mikiji,
Tsubouchi Takashi,
Tanaka Toshihiro,
Odani Toru,
Nagahama Sadamu,
Tanaka Tomoyuki,
Inoue Katsunari,
Saragai Seishi,
Nakamoto Shinsuke
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020715)41:14<2502::aid-anie2502>3.0.co;2-9
Subject(s) - stacking , intermolecular force , polymerization , halogen , ring (chemistry) , crystal structure , crystallography , chemistry , solid state , crystal (programming language) , hydrogen bond , polymer science , computer science , molecule , organic chemistry , polymer , alkyl , programming language
Stacking made to order : Weak intermolecular interactions such as 2D hydrogen‐bonding networks, aromatic‐ring stacking, and CH/π or halogen–halogen interactions account for the columnar organization of muconic and sorbic acid derivatives in the crystalline state (see picture). When the stacking distance is close to 5 Å these 1,3‐dienes undergo topochemical polymerization upon irradiation.