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A New Highly Efficient Ruthenium Metathesis Catalyst
Author(s) -
Wakamatsu Hideaki,
Blechert Siegfried
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020703)41:13<2403::aid-anie2403>3.0.co;2-f
Subject(s) - ruthenium , olefin metathesis , catalysis , metathesis , substituent , salt metathesis reaction , chemistry , grubbs' catalyst , olefin fiber , organic chemistry , polymerization , polymer
Olefin metathesis even at 0°C ! A phenyl substituent in the ruthenium catalyst 2 leads to greatly increased initiation rates in different metathesis reactions, for example, the cyclization of 1 to form 3 .