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Synthesis and Structural Characterization of Organometallic Cyclynes: Novel Nanoscale, Carbon‐Rich Topologies
Author(s) -
Laskoski Matthew,
Steffen Winfried,
Morton Jason G. M.,
Smith Mark D.,
Bunz Uwe H. F.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020703)41:13<2378::aid-anie2378>3.0.co;2-e
Subject(s) - characterization (materials science) , network topology , nanoscopic scale , content (measure theory) , carbon fibers , nanotechnology , computer science , molecule , materials science , chemistry , topology (electrical circuits) , organic chemistry , combinatorics , mathematics , computer network , algorithm , mathematical analysis , composite number
A combination of Pd‐ and Cu‐catalyzed couplings make the half‐wheels (see left and middle picture; Cp=C 5 H 5 ) and the seco‐wheel (right) shown here accessible. Single‐crystal structures of all three target molecules have been obtained.