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An Umpolung Approach to cis ‐Hyponitrite Complexes
Author(s) -
Arulsamy Navamoney,
Bohle D. Scott,
Imonigie Jerome A.,
Levine Seth
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020703)41:13<2371::aid-anie2371>3.0.co;2-j
Subject(s) - heterolysis , umpolung , chemistry , transition metal , bond cleavage , ferrocene , ligand (biochemistry) , thermal decomposition , kinetics , cleavage (geology) , stereochemistry , medicinal chemistry , organic chemistry , catalysis , materials science , electrochemistry , receptor , nucleophile , biochemistry , physics , electrode , quantum mechanics , composite material , fracture (geology)
Ligand formed by CN bond cleavage : Transition‐metal‐promoted heterolytic cleavage of the CN bond in 1 results in the formation of five new complexes of cis hyponitrite with Group 10 transition metals. The new complexes include [Ni( η 2 ‐O 2 N 2 )(dppf)] (dppf=1,1′‐bis(diphenylphosphanyl)ferrocene) which is structurally characterized and the thermal decomposition of which follows unimolecular kinetics.