Premium
Asymmetric Baeyer–Villiger Reaction with Hydrogen Peroxide Catalyzed by a Novel Planar‐Chiral Bisflavin
Author(s) -
Murahashi ShunIchi,
Ono Satoshi,
Imada Yasushi
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020703)41:13<2366::aid-anie2366>3.0.co;2-s
Subject(s) - hydrogen peroxide , catalysis , enantioselective synthesis , chemistry , planar , combinatorial chemistry , organic chemistry , photochemistry , computer graphics (images) , computer science
The chiral organocatalyst bisflavin 1 catalyzes the asymmetric Baeyer–Villiger reaction of cyclobutanones with H 2 O 2 (see scheme). The corresponding lactones are obtained with up to 74 % ee.