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Bifunctional Cp∩N Complexes—Unusual Structural Features and Electronic Coupling in Highly Preorganized Bimetallic Systems
Author(s) -
Röder Jens C.,
Meyer Franc,
Kaifer Elisabeth
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020703)41:13<2304::aid-anie2304>3.0.co;2-f
Subject(s) - bimetallic strip , bifunctional , chemistry , electron transfer , solid state , coupling (piping) , crystallography , stereochemistry , combinatorial chemistry , materials science , photochemistry , catalysis , organic chemistry , metallurgy
Fast electron transfer between the Mn centers in the mixed‐valent complex 1 , a dinuclear analogue of complexes with Cp′‐N‐ligands (Cp=C 5 H 5 ), supports the occurrence of cooperative effects in such highly preorganized bimetallic systems. An unsual η 1 : η 1 : η 5 coordination of the pyrazolate group is observed for K + 1 − in the solid state.