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The [ closo ‐2‐CB 6 H 7 ] − Ion: The First Representative of the 7‐Vertex Monocarbaborane Series
Author(s) -
Štíbr Bohumil,
Tok Oleg L.,
Milius Wolfgang,
Bakardjiev Mario,
Holub Josef,
Hnyk Drahomír,
Wrackmeyer Bernd
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020617)41:12<2126::aid-anie2126>3.0.co;2-6
Subject(s) - ion , chemistry , series (stratigraphy) , vertex (graph theory) , cluster (spacecraft) , computational chemistry , combinatorics , mathematics , organic chemistry , computer science , graph , biology , paleontology , programming language
Opening up closo ‐cluster chemistry : The first representative of the seven‐vertex closo monocarbaborane series, the [ closo ‐2‐CB 6 H 7 ] − ion (see structure), was isolated together with the [ closo ‐1‐CB 7 H 8 ] − ion from simple reactions between nido ‐1‐CB 8 H 12 and Et 3 N. Both ions exhibit high stability in air and are potentially useful for weakly coordinating anion chemistry.