Premium
sp Carbon Chains Surrounded by sp 3 Carbon Double Helices: A Class of Molecules that are Accessible by Self‐Assembly and Models for “Insulated” Molecular‐Scale Devices
Author(s) -
Stahl Jürgen,
Bohling James C.,
Bauer Eike B.,
Peters Thomas B.,
Mohr Wolfgang,
MartínAlvarez José M.,
Hampel Frank,
Gladysz John A.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020603)41:11<1871::aid-anie1871>3.0.co;2-v
Subject(s) - molecule , covalent bond , chemistry , self assembly , crystallography , carbon fibers , nanotechnology , stereochemistry , materials science , organic chemistry , composite number , composite material
Neither bonding interactions between the strands nor covalent bonds to metal templates dispersed throughout the strands are needed for the molecules presented here to adopt double‐helical structures (see picture). The molecules consist of rigid (CC) m chains that bridge two platinum atoms, which are in turn bridged by two diphosphane ligands of the formula Ar 2 P(CH 2 ) n PAr 2 .