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Hybrid Molecular Dumbbells: Bridging Polyoxometalate Clusters with an Organic π‐Conjugated Rod
Author(s) -
Lu Meng,
Wei Yongge,
Xu Bubin,
Cheung Calida FungChi,
Peng Zhonghua,
Powell Douglas R.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020503)41:9<1566::aid-anie1566>3.0.co;2-q
Subject(s) - polyoxometalate , conjugated system , bridging (networking) , materials science , nanotechnology , chemical physics , polymer chemistry , catalysis , chemistry , organic chemistry , polymer , computer network , computer science , composite material
Strong electronic interactions occur between the polyoxometalate (POM) clusters and the π electrons of the conjugated organic bridge in hybrid molecular dumbbells such as 1 which were synthesized by Pd‐catalyzed coupling reactions of organoimido‐substituted POMs.