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The First Isolable 4‐Silatriafulvene
Author(s) -
Sakamoto Kenkichi,
Ogasawara Jun,
Kon Yoshihiro,
Sunagawa Tatsuya,
Kabuto Chizuko,
Kira Mitsuo
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020415)41:8<1402::aid-anie1402>3.0.co;2-s
Subject(s) - chemistry , double bond , stereochemistry , crystallography , organic chemistry
Unique structural characteristics and reactivities caused by the less‐polar Si−C double bond in the 4‐silatriafulvene 1 were revealed by spectroscopic studies and X‐ray structural analysis. Compound 1 was isolated by applying a synthetic procedure using a sila‐Peterson‐type reaction.