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Alkene C−H Activations at Dinuclear Complexes Promoted by Oxidation
Author(s) -
Jiménez M. Victoria,
Sola Eduardo,
Caballero Javier,
Lahoz Fernando J.,
Oro Luis A.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020402)41:7<1208::aid-anie1208>3.0.co;2-f
Subject(s) - alkene , chemistry , organic chemistry , catalysis
Oxidation favors oxidative addition : This unexpected behavior has been observed in d 8 d 8 ‘open‐book' diiridium complexes with alkene ligands, which become C−H activating after oxidation with ferrocinium salts (see scheme).