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A New Mononuclear Iron( III ) Complex Containing a Peroxocarbonate Ligand
Author(s) -
Hashimoto Koji,
Nagatomo Shigenori,
Fujinami Shuhei,
Furutachi Hideki,
Ogo Seiji,
Suzuki Masatatsu,
Uehara Akira,
Maeda Yonezo,
Watanabe Yoshihito,
Kitagawa Teizo
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020402)41:7<1202::aid-anie1202>3.0.co;2-e
Subject(s) - chemistry , moiety , ligand (biochemistry) , chelation , nucleophile , ring (chemistry) , peroxide , stereochemistry , medicinal chemistry , metal , inorganic chemistry , catalysis , organic chemistry , receptor , biochemistry
Stabilization of a peroxocarbonate ligand by formation of a five‐membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis( μ ‐hydroxo)diiron( III ) complex with H 2 O 2 and CO 2 . Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO 2 . Hqn=quinaldic acid.