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The Determination of the Absolute Configurations of Diastereomers of ( S )‐Camphanoyl 3‐Hydroxy‐5‐oxohexanoic Acid Derivatives by X‐ray Crystallography
Author(s) -
Cheung KwaiMing,
Coles Simon J.,
Hursthouse Michael B.,
Johnson Neil I.,
Shoolingin – Jordan Peter M.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020402)41:7<1198::aid-anie1198>3.0.co;2-3
Subject(s) - diastereomer , chirality (physics) , chemistry , x ray , salicylic acid , stereochemistry , absolute configuration , crystallography , chiral symmetry , biochemistry , physics , quantum mechanics , nambu–jona lasinio model , quark
Chirality resolved : The stereochemistry of potential intermediates in the enzymic synthesis of 6‐methyl salicylic acid, ( R ) ‐ 1 and ( S ) ‐ 1 , has been determined by X‐ray crystallography of two corresponding crystalline intermediates ( S , S )‐ 2 (shown) and ( S , S )‐ 3 (not shown).