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The First “Naked” Primary Phosphanide Anion [ArPH] −
Author(s) -
Rudzevich Valentyn L.,
Gornitzka Heinz,
Miqueu Karinne,
Sotiropoulos JeanMarc,
PfisterGuillouzo Geneviève,
Romanenko Vadim D.,
Bertrand Guy
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020402)41:7<1193::aid-anie1193>3.0.co;2-x
Subject(s) - substituent , trifluoromethyl , steric effects , chemistry , ion , primary (astronomy) , salt (chemistry) , stereochemistry , organic chemistry , alkyl , physics , astronomy
The electronic and steric properties of the 2,6‐bis(trifluoromethyl)phenyl (Ar f ) substituent stabilize a naked dicoordinate phosphorus anion (see scheme) in the primary phosphanide salt [K([15]crown‐5) 2 ][Ar f PH], both in the solid state and in solution.