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Selective Direct Synthesis of Organofunctionalized Dialkylgermanes from Solvochemically Activated Germanium
Author(s) -
Schlecht Sabine
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020402)41:7<1178::aid-anie1178>3.0.co;2-7
Subject(s) - germanium , germanium compounds , halogen , alkyl , coupling (piping) , materials science , chemistry , combinatorial chemistry , silicon , organic chemistry , metallurgy
Kinetic inertness overcome : The selective coupling of Ge−E bonds (E=halogen, C) can be achieved at 130°C by direct synthesis from activated germanium. Alkyl bromides with an additional carbonyl function (see scheme) can be converted in a controlled manner into dibromodiorganogermanes.