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Rational Design of Homochiral Solids Based on Two‐Dimensional Metal Carboxylates
Author(s) -
Cui Yong,
Evans Owen R.,
Ngo Helen L.,
White Peter S.,
Lin Wenbin
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020402)41:7<1159::aid-anie1159>3.0.co;2-5
Subject(s) - enantiopure drug , sbus , metal , rational design , bridging (networking) , metal organic framework , carboxylate , alkoxy group , computer science , chemistry , combinatorial chemistry , stereochemistry , materials science , enantioselective synthesis , nanotechnology , organic chemistry , computer network , catalysis , alkyl , adsorption
A chiral two‐dimensional network is the basis for the structure of a homochiral solid exploiting metal–carboxylate coordination. The synthesis involved enantiopure bridging ligands and metal–organic secondary building units (SBUs), and resulted in ethoxy‐protected BINOL functionalities pointing into the cavities in this crystalline chiral zeolitic material (see picture).