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A Highly Efficient Catalyst for the Telomerization of 1,3‐Dienes with Alcohols: First Synthesis of a Monocarbenepalladium( 0 )–Olefin Complex
Author(s) -
Jackstell Ralf,
Gómez Andreu Mario,
Frisch Anja,
Selvakumar Kumaravel,
Zapf Alexander,
Klein Holger,
Spannenberg Anke,
Röttger Dirk,
Briel Oliver,
Karch Ralf,
Beller Matthias
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020315)41:6<986::aid-anie986>3.0.co;2-m
Subject(s) - telomerization , olefin fiber , catalysis , chemistry , organic chemistry , combinatorial chemistry
Industrial reaction improved : The first monocarbenepalladium( 0 )–olefin complex has been isolated and characterized (see structure; Pd orange, N green, S yellow, O blue). The complex exhibited unprecedented high catalyst productivity and selectivity for industrially important telomerization reactions (the dimerization of 1,3‐dienes in the presence of a nucleophile, in this case an alcohol).