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A Supramolecular Array of Fullerenes by Quadruple Hydrogen Bonding
Author(s) -
Sánchez Luis,
Rispens Minze T.,
Hummelen Jan C.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020301)41:5<838::aid-anie838>3.0.co;2-f
Subject(s) - supramolecular chemistry , fullerene , moiety , monomer , nanotechnology , hydrogen bond , block (permutation group theory) , chemistry , materials science , polymer science , polymer chemistry , stereochemistry , molecule , organic chemistry , polymer , combinatorics , mathematics
Bucky balls and chains : The quadruple hydrogen‐bonded fullerene array 1 was synthesized and fully characterized. In the highly dynamic polymeric state, the chemical integrity of the monomeric moiety is fully preserved, also with respect to its redox and UV/Vis behavior. Hence, 1 can potentially serve as a building block in supramolecular electronics.