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Carbonyltris(trifluoromethyl)borane, (CF 3 ) 3 BCO, An Unusual Boron Carbonyl
Author(s) -
Terheiden Annegret,
Bernhardt Eduard,
Willner Helge,
Aubke Friedhelm
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020301)41:5<799::aid-anie799>3.0.co;2-s
Subject(s) - borane , chemistry , trifluoromethyl , boron , electrophile , medicinal chemistry , carbon atom , hydrolysis , organic chemistry , catalysis , alkyl
By hydrolysis of a single CF 3 group in concentrated sulfuric acid, the new boron carbonyl (CF 3 ) 3 B−CO compound (see molecular structure) is obtained from K[B(CF 3 ) 4 ]. (CF 3 ) 3 B−CO exhibits rather unusual properties and bears an electrophilic carbonyl carbon atom.