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A Nanoporous Metal–Organic Framework Based on Bulky Phosphane Ligands
Author(s) -
Xu Xingling,
Nieuwenhuyzen Mark,
James Stuart L.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020301)41:5<764::aid-anie764>3.0.co;2-n
Subject(s) - nanoporous , solvent , metal , hexagonal crystal system , organic solvent , polymer , materials science , chemistry , polymer chemistry , chemical engineering , nanotechnology , organic chemistry , engineering , crystallography
No interpenetration : The use of bulky phosphane ligands allows the preparation of a non‐interpenetrating two‐dimensional nanoporous structure with hexagonal channels (see picture). In the as‐synthesized polymer these channels are saturated with solvent, however, this solvent can be exchanged for other solvents which in turn can be removed by heating under vacuum without collapse of the structure.