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Paramagnetic Keplerate “Necklaces” Synthesized by a Novel Room‐Temperature Solid‐State Reaction: Controlled Linking of Metal‐Oxide‐Based Nanoparticles
Author(s) -
Müller Achim,
Das Samar K.,
Talismanova Marina O.,
Bögge Hartmut,
Kögerler Paul,
Schmidtmann Marc,
Talismanov Sergei S.,
Luban Marshall,
Krickemeyer Erich
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020215)41:4<579::aid-anie579>3.0.co;2-z
Subject(s) - covalent bond , oxide , metal , nanoparticle , molybdenum , paramagnetism , cluster (spacecraft) , molybdenum oxide , crystal (programming language) , materials science , solid state , chemical engineering , chemistry , crystal structure , nanotechnology , crystallography , inorganic chemistry , organic chemistry , physics , quantum mechanics , engineering , computer science , programming language
Crystal engineering with nanoobjects? Spherical structurally well‐defined molybdenum‐oxide‐based giant clusters can be appropriately functionalized to a crystalline material with the remarkable property of having discrete cluster units which get covalently linked to form chains (see picture) through Fe−O−Mo bonds after having approached each other as a result of the release of crystal water upon drying.