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Rearrangement of 3‐Rhoda‐1,2‐dioxolanes to Rhodium Formylmethyl Hydroxy Complexes
Author(s) -
Krom Monique,
Coumans Ruud G. E.,
Smits Jan M. M.,
Gal Anton W.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020215)41:4<575::aid-anie575>3.0.co;2-e
Subject(s) - rhodium , acetaldehyde , chemistry , oxide , political science , catalysis , organic chemistry , ethanol
Instead of direct conversion into a metal oxo complex and acetaldehyde or ethylene oxide, as was proposed earlier for 3‐metalla‐1,2‐dioxolanes, 3‐rhoda‐1,2‐dioxolanes 1 + have now been found to rearrange to rhodium formylmethyl hydroxy complexes 2 + upon exposure to light or protons.