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Ruthenium‐Catalyzed Oxidative Heck Reactions
Author(s) -
Farrington Edward J.,
Brown John M.,
Barnard C. F. J.,
Rowsell E.
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020104)41:1<169::aid-anie169>3.0.co;2-s
Subject(s) - ruthenium , chemistry , halide , catalysis , aryl , heck reaction , combinatorial chemistry , catalytic cycle , compatibility (geochemistry) , organic chemistry , palladium , chemical engineering , alkyl , engineering
Aryl boronic acids can undergo a Heck‐type reaction catalyzed by Ru II in the presence of Cu II , which serves as a reoxidant in each cycle (see scheme, step 1). Compatibility with halide substituents offers attractive synthetic potential (step 2).