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A Pillared‐Layer Coordination Polymer Network Displaying Hysteretic Sorption: [Cu 2 (pzdc) 2 (dpyg)] n (pzdc= Pyrazine‐2,3‐dicarboxylate; dpyg=1,2‐Di(4‐pyridyl)glycol)
Author(s) -
Kitaura Ryo,
Fujimoto Kentaro,
Noro Shinichiro,
Kondo Mitsuru,
Kitagawa Susumu
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20020104)41:1<133::aid-anie133>3.0.co;2-r
Subject(s) - sorption , pyrazine , coordination polymer , desorption , layer (electronics) , polymer , crystallography , adsorption , materials science , crystal (programming language) , crystal structure , inorganic chemistry , chemistry , stereochemistry , nanotechnology , organic chemistry , composite material , computer science , programming language
A hysteretic adsorption and desorption profile (right) accompanied by a transformation of the crystal structure is observed for the title coordination polymer, which possesses a pillared‐layer structure (left), on exposure to H 2 O or MeOH vapor under pressure.