Heat Capacity of the Mixed‐Valence Complex {[( n ‐C 3 H 7 ) 4 N][Fe II Fe III (dto) 3 ]} ∞ , Phase Transition because of Electron Transfer, and a Change in Spin‐State of the Whole System | Zendy

Nakamoto Tadahiro | Zendy; Miyazaki Yuji | Zendy; Itoi Miho | Zendy; Ono Yuuki | Zendy; Kojima Norimichi | Zendy; Sorai Michio | Zendy

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Heat Capacity of the Mixed‐Valence Complex {[( n ‐C 3 H 7 ) 4 N][Fe II Fe III (dto) 3 ]} ∞ , Phase Transition because of Electron Transfer, and a Change in Spin‐State of the Whole System

Author(s) -

Nakamoto Tadahiro,

Miyazaki Yuji,

Itoi Miho,

Ono Yuuki,

Kojima Norimichi,

Sorai Michio

Publication year - 2001

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/1521-3773(20011217)40:24<4716::aid-anie4716>3.0.co;2-5

Subject(s) - spin crossover , valence (chemistry) , phase transition , condensed matter physics , electron transfer , heat capacity , electron , chemistry , crossover , chemical physics , physics , thermodynamics , quantum mechanics , organic chemistry , artificial intelligence , computer science

Not a classical spin‐crossover : The heat capacity of the mixed‐valence complex {[( n ‐C 3 H 7 ) 4 N][Fe II Fe III (dto) 3 ]} ∞ (dto=dithiooxalato, see scheme) exhibits a phase transition at 122.4 K as a result of electron transfer, and gives insight into the cooperative phenomena exhibited by the multifunctional material.

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