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Formation and Stabilization of a Decanuclear Cu II Wheel Linked by Chloride and O⋅⋅⋅H−N Hydrogen Bonds
Author(s) -
Chang CheHao,
Hwang Kuo Chu,
Liu ChaoShiuan,
Chi Yun,
Carty Arthur J.,
Scoles Ludmila,
Peng ShieMing,
Lee GeneHsiang,
Reedijk Jan
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20011217)40:24<4651::aid-anie4651>3.0.co;2-x
Subject(s) - hydrogen bond , chemistry , crystallography , ring (chemistry) , chloride , copper , nitrogen , polymer chemistry , inorganic chemistry , molecule , organic chemistry
Copper gets into the ring : A decanuclear cyclic Cu II complex is synthesized by direct treatment of CuCl 2 with a fluorinated amino alcoholate containing one secondary and one tertiary nitrogen donor (see space‐filling diagram; Cu light blue, Cl yellow, O red, N dark blue, C gray). Possible factors that lead to the self‐assembly of the unique molecular wheel are discussed.