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Molecular Insight Into Surface Organometallic Chemistry Through the Combined Use of 2D HETCOR Solid‐State NMR Spectroscopy and Silsesquioxane Analogues
Author(s) -
Chabanas Mathieu,
Quadrelli Elsje Alessandra,
Fenet Bernard,
Copéret Christophe,
ThivolleCazat Jean,
Basset JeanMarie,
Lesage Anne,
Emsley Lyndon
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20011203)40:23<4493::aid-anie4493>3.0.co;2-x
Subject(s) - silsesquioxane , nuclear magnetic resonance spectroscopy , solid state , spectroscopy , chemistry , solid state nuclear magnetic resonance , organometallic chemistry , crystallography , polymer science , materials science , nanotechnology , polymer chemistry , stereochemistry , organic chemistry , physics , crystal structure , nuclear magnetic resonance , quantum mechanics , polymer
Feher cage analogues , such as 1 , provide easy access to models of surface structures such as 2 , and give a better understanding of surface reactions. In addition, surface complexes such as 2 can be fully characterized by high‐resolution 1D and 2D solid‐state NMR spectroscopy.