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Oxidizing Polymers: A Polymer‐Supported, Recyclable Hypervalent Iodine( V ) Reagent for the Efficient Conversion of Alcohols, Carbonyl Compounds, and Unsaturated Carbamates in Solution
Author(s) -
Sorg Gerhard,
Mengel Anne,
Jung Günther,
Rademann Jörg
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20011203)40:23<4395::aid-anie4395>3.0.co;2-r
Subject(s) - hypervalent molecule , oxidizing agent , reagent , chemistry , alcohol oxidation , ketone , polymer , organic chemistry , iodine , polymer chemistry , combinatorial chemistry , catalysis
The oxidation of various alcohols and cyclization of an olefinic carbamate succeeds with the first polymer‐supported iodine( V ) reagent (see scheme). The novel oxidizing polymer oxidizes sensitive and complex alcohols, including protected amino alcohols, efficiently in good to excellent yields. In addition, the α , β ‐dehydration of a ketone is demonstrated.