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Efficient, Catalytic, Aerobic Oxidation of Alcohols with Octahedral Molecular Sieves
Author(s) -
Son YoungChan,
Makwana Vinit D.,
Howell Amy R.,
Suib Steven L.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20011119)40:22<4280::aid-anie4280>3.0.co;2-l
Subject(s) - molecular sieve , octahedron , catalysis , selectivity , manganese , alcohol oxidation , environmentally friendly , chemistry , inorganic chemistry , organic chemistry , ion , ecology , biology
Mixed‐valent manganese octahedral molecular sieves K‐OMS‐2 and H‐K‐OMS‐2 are used to oxidize a wide range of alcohols with 100 % selectivity and 90–100 % conversion in most cases. The reaction (see scheme) is aerobic, catalytic, mild, efficient, stable, inexpensive, selective, and environmentally friendly.