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Yttrate Metathesis: Ligand Design for the Controlled Synthesis of f‐Block Heterobimetallic Compounds
Author(s) -
Hill Michael S.,
Hitchcock Peter B.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20011105)40:21<4089::aid-anie4089>3.0.co;2-o
Subject(s) - metathesis , ligand (biochemistry) , block (permutation group theory) , library science , chemistry , combinatorial chemistry , stereochemistry , computer science , organic chemistry , mathematics , receptor , biochemistry , geometry , polymerization , polymer
The use of a Me 2 Si‐bridged amido‐cyclopentadienyl ligand containing pendant pyridine functionality allows clean “yttrate metathesis” to occur and the synthesis of the unusual C 2 ‐symmetric Y/Cu bimetallic compound 1 .