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Discrete Mixed‐Valence Metal Chains: Iridium Pyridonate Blues
Author(s) -
Tejel Cristina,
Ciriano Miguel A.,
Villarroya B. Eva,
Gelpi Raquel,
López José A.,
Lahoz Fernando J.,
Oro Luis A.
Publication year - 2001
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20011105)40:21<4084::aid-anie4084>3.0.co;2-h
Subject(s) - blues , valence (chemistry) , business , finance , chemistry , economics , management , organic chemistry
Binuclear complexes with head‐to‐tail (HT) configurations are appropriate for building tetrametallic chains, contrary to previous speculations. Moreover, the isolated HT,HH tetrametallic species are converted into the thermodynamically more stable HH,HH compounds (see scheme).